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(6)ch(6)ch 3c H2 CBR 2ch 3(7)ch 3c H2 ch 3(6)ch(6)ch 3c H2 CBR 2ch 3(7)ch 3c H2 ch 2ch 3 2。(1) 2.(1) 2 (5) 4.80 *.(3) (4) (6)不溶于水。80 * 7.5%/1 = 680 * 47.5%/19 = 2 C第二章有机化合物的结构本质和结构关系2324 SP [6] SP第四章开链(1) 2-甲基-4,5-二乙基庚烷(2) 3-甲基戊烷υ(顺式)-3-甲基-3-己烯或Z-3-甲基-3-己烯2.3 1。(1) sp ⑶ sp烃(3) 2,4-二甲基-3-乙基戊烷(12) 3-甲基-1-庚烯-5-炔CH3(1)ch 3c H2 chch(CH2)4c H3(2)(CH3)2ch2 ch 2ch 3 C2 HC 2 H5 H3 ch 3(3)(CH3(3)(CH3)2 .2 CH 3c H2 CH = C(CH2)3c H3 C2 H5 C2 H5(CH3)2CHC—CH(CH2)3c H3 H3C H H C C CH 2ch2 CH 3 C2 H5(7)ch2ch 3(8)(CH3)2CHC—C—CCH(CH(7)ch2ch 3(8)(CH3)2CHC—C—C—CCH(CH3)2 H3C(9)7。H =C〈H CH3 H5C2 C2H5 (10) C C \ o "当前文档" H3C XCH3 ClCl H Cl11。cl(1)ch 3c HCH 2ch 2ch 3(2)(CH3)2CCH 2ch 3 Br CH3(3)(CH3)2CCH(CH3)2(4)ch 3c H2 cc 2h 5 1 Br 1 Br(3)ch 3c HCH 2ch 3 12。⑴(CH3)2cch 2ch 3(2)ch 3c H2 ch 2ch 3 OH(4)ch 3c ooh+(4)ch 3c ooh+H3C c—o H3CZ(5)ch 3c H2 chch 3 oso 3h ch 3c H2 chch 3 OH 0 2。2.2.2.br(8)(CH3)2CCH—CH2+(CH3)2C _ chch 2 br CH—CH2(9)(CH 2 cyh CH 2)n+(CH?—C) n Cl Cl (10) I CHO 14。(5)>(3)>(2)>(1)>(4)CH = CHCHCH & gt;(CH3) 3C+>CHCHKJHCH & gtChchchkjh > (CH3) 2ch (CH2 16。(1) 17.21,即:1-戊烯* V溴褪色Br 2/CCI 4 1-戊烯在室温下,远离光* V溴。X丁烷”X Ag(NH 3)2+ X 1,3-丁烯1-己炔BH/CCI4溴褪色Br2/CCl4 V溴褪色室温下,远离光Ag(NH 3 ear X V灰白色J (2) CH-CHH2O [CH2-CHOH] H2SO4。HgSO4 ■CH3CHO KMnO 4/H 10。(1)CH-CH = CH CHCOOH(2)CH-gCH+HBr(2 imol)CH QB dch HBr(1 moi)B〔2(3)CH-g CH-c = CH CH c br CH br第四章环烃6 6,(3)(1)(2)34cl(1)br br clo 2 NBR(5)cooh+NO2(9)(10)。10 6-3H H Br n H CH CHj CI I CH3(2)Cl⑷H3C Cl+(3)X(4)V(5)V(6)V CH3(3)(CH3)2C CH(CH3)2 C2 H5 Br C2 H5(6)(CH3)3C—?-a cooh (7) CH3 COCH 3CH3 L COTIBR-IC皿Te-—A *第六章光学同构C(CH 3)3 SO3H 7。(2)芳香苯/无水AICI 3NHCOCH 32。(1)X(2)X(8)1mol cl 2/HCH 3 ch 2 oh h-och 3 CII sch。奥赫乔(1)..7Fch3-trans Br cis ]CHiC late 7。]20 18.8 D c l 5.678 2,4,20 1 66 '白J AgNO 3/乙醇,室温x白J >。\ AgNO 3/乙醇,热一个?X J X第七章卤代烃RMB(LJCIHCHBRCIBBR C2 ihc = CIIC IIS CCH(2)c 1CH = chch 2()CH3。

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